Metal salts assisted thermoplastic polymer NIPAM in-situ carbonization on porous silica microspheres surface

Ex Situ Integration of Multifunctional Porous Polymer Monoliths into Thermoplastic Microfluidic Chips.

A unique method for incorporating functional porous polymer monolith elements into thermoplastic microfluidic chips is described. Monolith elements are formed in a microfabricated mold, rather than within the microchannels, and chemically functionalized off chip before insertion into solvent-softened thermoplastic microchannels during chip assembly. Because monoliths may be trimmed prior to fin...

Plasmon-assisted transparency in metal-dielectric microspheres.

We present a theoretical analysis of light scattering from a layered metal-dielectric microsphere. The system consists of two spherical resonators coupled through concentric embedding. Solving for the modes of this system, we find that near an avoided crossing the scattering cross section is dramatically suppressed, exhibiting a tunable optical transparency. Similar to electromagnetically induc...

Cyclodextrin-based Porous Silica Materials as in Situ Chemical “Nanoreactors” for the Preparation of Variable Metal-Silica Hybrids

Inclusion complexes of cyclodextrins with organometallic coordination compounds of Pd, Pt, Rh, Fe, Ni, and Ru have been used to produce porous metal-silica hybrid materials. The cyclodextrins are templates for the structure of the silica and lead to a uniform “wormtype” pore system. After the templating step the organometallic compounds can be employed as in situ precursors for the preparation ...

Nanofibrous microspheres via emulsion gelation and carbonization.

Nanofibrous hydrogel microspheres are formed by pH gelation of perylene diimide derivatives in emulsion droplets. These microspheres are freeze-dried and subsequently carbonized to produce discrete N-doped nanofibrous carbon microspheres. The carbon microspheres show high performance as electrode materials for supercapacitors.

A general and facile synthesis strategy towards highly porous carbons: carbonization of organic salts